Journal of Engineering
Volume 2022 (2022), Article ID 6963417, 8 pages
https://doi.org/10.1155/2022/6963417
Effect of Annealing on the Microstructure, Hardness, Electrical Conductivity, and Corrosion of Copper Material before Accumulative Roll Bonding Processes
Correspondence should be addressed to M. Pita
Received 16 May 2022; Revised 25 August 2022; Accepted 7 September 2022; Published 29 September 2022
Academic Editor: Chong Leong Gan
Copyright © 2022 M. Pita and L. Lebea. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract
Copper is one of the first metals to ever be mined and used by humans, and since the dawn of civilization, it has made important contributions to behavioral science. The exploration of copper has provided knowledge of nonfuel minerals and has consequently improved society. The objective of this paper is to investigate the effect of annealing on the microstructure, mechanical properties, and corrosion of copper material before undergoing an accumulative roll bonding process (ARB). The material was heated to 600°C and cooled with water before being rolled by a two-roller rolling machine. The second ARB experiment was conducted on copper material without annealing. The samples were characterized by a light microscope (LM). The ASTM E384 test method was followed during the hardness test. The results show that annealing and applying two passes of the ARB process reduce the grain size by 37%, which is significant. It also increases copper hardness by 65% and increases its electrical conductivity by 2.6%. Additionally, the results show that the open circuit potential during the first pass heated sample was −0.07237 V; this increased by 22.16% with the second pass heated sample.
1. Introduction
Presently, copper is used in building construction, the production of industrial machinery, power generation and transmission, electronic product manufacturing, and transportation vehicles [1]. Lightweight materials are the focus of the development of novel structural materials, as they bear the potential to reduce energy consumption in mobile applications while retaining functionality [2]. The most common severe plastic deformation (SPD) processes are equal channel angular pressing (ECAP), high-pressure torsion (HPT), and accumulative roll bonding (ARB) [3]. Accumulative roll bonding is known as one of the more severe plastic deformation processes, which can give a much larger equivalent strain than that of normal plastic deformation, and generally, the equivalent strain becomes larger than 4 in SPD processes [4]. The ARB process reduces material thickness by 50% in one pass. Ultrafine grained (UFG) metals and alloys processed by severe plastic deformation techniques have been reported to have superior mechanical properties, such as high strength and hardness, good ductility, and excellent superplasticity at lower temperatures and higher strains [5]. During the monotonic deformation of conventional materials to nanomaterials, the material grain size decreases. The decrease in material grain size brings about an increase in the material’s properties [6].
Several studies have been conducted regarding the microstructure, mechanical properties, and corrosion of copper material by an accumulative roll bonding process. The accumulative roll bonding of pure copper and interstitial free steel study [7] was conducted at an elevated temperature, and the results of this study showed that an ARB process at a lower temperature results in higher hardness in copper and steel sheets; however, it may lead to its appearance as an unbonded area, which is undesirable. A study of continuous extrusion and the roll forming of copper strips found that after continuous extrusion, a homogeneously distributed and equiaxed grain microstructure can be formed in copper strip billets with an average grain size of about 80 μm. The grains of the copper strips were stretched clearly during rolling and along the rolling direction to form a stable orientation, and after rolling, the grain boundaries are still relatively clear to see [8]. It was reported that the hardness value of the copper layer increased sharply in the first cycle and then remained constant for the next two cycles. It later rose over the following four stages, during which Cu/Sn multilayer composite was developed through accumulative roll bonding [9]. The microstructure and mechanical properties of pure copper were subjected to skin pass asymmetric rolling after 300°C annealing, and it was found that the grains were refined to 4 μm from 85 μm. It was also reported that the strength of the sheets increased dramatically, but at the same time, their ductility decreased drastically [10].
Corrosion of metal in the presence of water is a common problem across many industries [11]. Modifications to the copper strip corrosion test for the measurement of sulfur-related corrosion research were performed [12], and another study conducted testing of copper strip corrosion for different fluid samples [13]. Copper is a useful material that has been used for different applications; therefore, it is imperative to enhance its properties. This paper investigates the effect of heating copper material before ARB processes in order to improve its properties.
2. Materials
The materials used in this study were copper strips that were 80 mm long, 15 mm wide, and 1.187 mm in thickness. The chemical composition, which is presented in Table 1 was obtained using the following method. Three spark analyses were done per sample by using glow discharge optical emission spectroscopy (GD-OES). The GD-OES was first calibrated by using a copper standard (parent sample) before analysis. An average was then calculated from the three analysis results, trace elements were filtered from the raw data and only major alloying elements for copper alloys were included in the results.