Photocatalytic Properties of Tin Oxide and Antimony-Doped Tin Oxide Nanoparticles

Table 3

(a) 𝐑_max¹⁶³⁷, 𝐑^∗max1637, 𝐊^∗max1637, and Φ_𝝀/Φ_𝟑𝟏𝟓 measured at 1637 cm⁻¹ using different wavelengths of irradiation (λ). Sb doping: 7%.^{a, b} (b) 𝐑^∗_ini, 𝐊^∗_ini, 𝐊^∗_ini/𝐊^∗max and 𝐊^∗_ini/𝐊^∗_ini measured at 1637 cm⁻¹, and 1620 cm⁻¹ using different wavelengths of irradiation (λ). Sb doping: 7%.^{a, b} (c) 𝐑^∗_ini and 𝐊^∗_ini measured at 1637 cm⁻¹ and 1620 cm⁻¹ different wavelengths of irradiation (λ). Sb doping: 0%.^{a, b}

(a)

λ[nm]	𝑅max1637[mol m^−3 s^−1]	𝑅^∗max1637 [mol m^−3 s^−1]	𝐾^∗max1637 [m^3/2 s^−1/2 J^−1/2]	Φ𝜆/Φ315
315	3.0	4.2	3×10^−4	1
365	0.65	0.65	1×10^−4	0.4
408	0.025	0.025	0.04×10^−4	0.01
545	0.035	0.033	0.07×10^−4	0.02
650	0.081	0.23	1×10^−4	0.3

^aMPS/Sb : SnO₂= 0.19 g/g; 𝑐_particle=10 vol.%.
^b𝑅^∗max1637values are 𝑅^∗max1637 values corrected for differences in 𝐼₀, and these 𝑅^∗max1637 values are within experimental error equal to 𝑅^∗max1620. The 𝐾^∗max1637 values were calculated from the 𝑅^∗max1637 values.

(b)

𝜆 [nm]	𝑅^∗ini^1637 [mol m^−3 s^−1]	𝑅^∗ini^1620 [mol m^−3 s^−1]	𝐾^∗ini^1637 [m^3/2 s^−1/2 J^−1/2]	𝐾^∗ini^1620[m^3/2 s^−1/2J^−1/2]	𝐾^∗ini^1637/𝐾^∗max1637	𝐾^∗ini^1637/𝐾^∗ini^1620
315	2.58	1.50	2.0×10^−4	1.0×10^−4	0.5	1.5
365	0.47	0.39	0.5×10^−4	0.3×10^−4	0.6	1.5
408	0.023	0.015	0.03×10^−4	0.02×10^−4	0.7	1.5
545	0.023	0.015	0.04×10^−4	0.03×10^−4	0.6	1.3
650	0.180	0.132	0.6×10^−4	0.44×10^−4	0.6	1.4

^aMPS/Sb : SnO₂= 0.19 g/g; 𝑐_particle = 10 vol%.
^bThe 𝐾_max1637 values used are shown in Table 3(a). The 𝐾^∗_ini corrected for differences in 𝐼₀. The values 𝐾^∗_ini were calculated from the corresponding 𝑅^∗_ini values.

(c)

𝜆 [nm]	𝑅^∗ini^1637[mol m^−3 s^−1]	𝑅^∗ini^1620 [mol m^−3 s^−1]	𝐾^∗ini^1637 [mol m^−3/2 s^−1/2]	𝐾^∗ini^1620 [mol m^−3/2 s^−1/2 J^−1/2]	𝐾^∗ini^1637/𝐾^∗ini^1620
315	6.4	3.5	3.4×10^−4	1.90×10^−4	1.8
365	0.39	0.21	0.7×10^−4	0.4×10^−4	1.9
408	0.016	0.0081	0.04×10^−4	0.02×10^−4	2.0
545	0.061	0.037	0.26×10^−4	0.16×10^−4	1.7
650	0.31	0.23	6×10^−4	4×10^−4	1.5

^aMPS/Sb : SnO₂ = 0.19 g/g; 𝑐_particle=10 vol%.
^bThe 𝑅^∗_ini are 𝑅_ini values corrected for differences in 𝐼₀. The 𝐾^∗_ini values and 𝐾^∗_ini ratios were calculated from the corresponding 𝑅^∗_ini values shown.