Review Article

Endogenous Generation of Singlet Oxygen and Ozone in Human and Animal Tissues: Mechanisms, Biological Significance, and Influence of Dietary Components

Figure 14

Proposed mechanism for the reaction of the 13-hydroperoxide of linoleic acid 34 with lysine (RNH2) to form Nε–(hexanoyl) lysine 74 via a dioxetane intermediate 69. The asterisk indicates that the carbonyl is in excited state.