Crystal Structure of Poly[(acetone-O)-3-((3,4-dimethoxyphenyl)(4-hydroxy-2-oxo-2H-chromen-3-yl)methyl)-(2-oxo-2H-chromen-4-olate)sodium]

Table 7

Torsion angles (°) for Compound 1.

O2′–Na1–O2–C2	41.3(13)	O1–C2–C3–C4	2.8(11)
O7–Na1–O2–C2	−26(4)	O2–C2–C3–C1	1.5(12)
O5–Na1–O2–C2	−164.4(13)	O1–C2–C3–C1	−178.4(6)
O4–Na1–O2–C2	133.5(12)	C4–C3–C1–C3′	83.3(10)
O3^iv –Na1–O2–C2	−58.9(13)	C2–C3–C1–C3′	−95.5(8)
O2–Na1–O5–C13	−86.1(6)	C4–C3–C1–C16^v	−52.9(9)
O2′–Na1–O5–C13	−9.4(9)	C2–C3–C1–C16^v	128.4(7)
O7–Na1–O5–C13	97.5(6)	O1–C8A–C8–C7	180.0(8)
O4–Na1–O5–C13	17.1(5)	C4A–C8A–C8–C7	−2.4(13)
O3^iv –Na1–O5–C13	−179.6(5)	C8A–C8–C7–C6	2.8(13)
O2–Na1–O5–C10	74.8(6)	C8–C7–C6–C5	−3.9(13)
O2′–Na1–O5–C10	151.6(7)	Na1–O7–C17–C19	−44(2)
O7–Na1–O5–C10	−101.5(7)	Na1–O7–C17–C18	132.0(15)
O4–Na1–O5–C10	178.1(7)	C7–C6–C5–C4A	4.6(13)
O3^iv –Na1–O5–C10	−18.6(7)	O1–C8A–C4A–C5	−179.5(7)
O2–Na1–O7–C17	−71(4)	C8–C8A–C4A–C5	3.0(12)
O2′–Na1–O7–C17	−138.5(14)	O1–C8A–C4A–C4	−2.7(11)
O5–Na1–O7–C17	66.7(14)	C8–C8A–C4A–C4	179.8(7)
O4–Na1–O7–C17	128.9(14)	C6–C5–C4A–C8A	−4.1(11)
O3^iv –Na1–O7–C17	−38.1(14)	C6–C5–C4A–C4	179.3(8)
O2–Na1–O4–C12	65.7(6)	Na1–O2′–C2′–O1′	160.9(7)
O2′–Na1–O4–C12	153.2(5)	Na1–O2′–C2′–C3′	−22.1(15)
O7–Na1–O4–C12	−116.2(6)	C8A′–O1′–C2′–O2′	−175.6(7)
O5–Na1–O4–C12	−15.4(5)	C8A′–O1′–C2′–C3′	7.1(10)
O3^iv –Na1–O4–C12	−73.3(9)	Na1^ii –O3–C4–C3	−176.9(6)
O2–Na1–O4–C9	−105.7(6)	Na1^ii –O3–C4–C4A	3.6(12)
O2′–Na1–O4–C9	−18.2(7)	C2–C3–C4–O3	174.7(7)
O7–Na1–O4–C9	72.4(7)	C1–C3–C4–O3	−3.9(12)
O5–Na1–O4–C9	173.2(7)	C2–C3–C4–C4A	−5.7(10)
O3^iv –Na1–O4–C9	115.3(8)	C1–C3–C4–C4A	175.6(7)
O2–Na1–O2′–C2′	−18.1(10)	C8A–C4A–C4–O3	−174.8(7)
O7–Na1–O2′–C2′	156.8(10)	C5–C4A–C4–O3	1.8(11)
O5–Na1–O2′–C2′	−94.9(11)	C8A–C4A–C4–C3	5.7(11)
O4–Na1–O2′–C2′	−118.4(10)	C5–C4A–C4–C3	−177.7(7)
O3^iv –Na1–O2′–C2′	75.6(10)	O2′–C2′–C3′–C4′	174.8(8)
C10–O5–C13–C14	2.2(12)	O1′–C2′–C3′–C4′	−8.4(11)
Na1–O5–C13–C14	163.3(6)	O2′–C2′–C3′–C1	−2.8(12)
C10–O5–C13–C12	−178.4(7)	O1′–C2′–C3′–C1	174.0(6)
Na1–O5–C13–C12	−17.3(9)	C3–C1–C3′–C4′	−72.1(10)
C9–O4–C12–C11	5.9(11)	C16^v –C1–C3′–C4′	63.3(9)
Na1–O4–C12–C11	−165.7(6)	C3–C1–C3′–C2′	105.4(8)
C9–O4–C12–C13	−175.2(7)	C16^v –C1–C3′–C2′	−119.1(8)
Na1–O4–C12–C13	13.2(9)	C2′–C3′–C4′–O3′	−177.2(7)
C14–C13–C12–O4	−178.6(7)	C1–C3′–C4′–O3′	.3(12)
O5–C13–C12–O4	1.9(9)	C2′–C3′–C4′–C4A′	3.7(11)
C14–C13–C12–C11	.4(11)	C1–C3′–C4′–C4A′	−178.8(7)
O5–C13–C12–C11	−179.1(7)	C4A′–C5′–C6′–C7′	1.3(14)
O4–C12–C11–C16	177.0(7)	C5′–C6′–C7′–C8′	−.7(15)
C13–C12–C11–C16	−1.9(11)	C6′–C7′–C8′–C8A′	−1.9(14)
Na1–O2–C2–O1	176.4(9)	C6′–C5′–C4A′–C8A′	.8(12)
Na1–O2–C2–C3	−3.4(19)	C6′–C5′–C4A′–C4′	−178.1(8)
C8A–O1–C2–O2	−179.6(7)	O3′–C4′–C4A′–C8A′	−176.8(7)
C8A–O1–C2–C3	.3(10)	C3′–C4′–C4A′–C8A′	2.4(11)
C12–C11–C16–C15	1.3(11)	O3′–C4′–C4A′–C5′	2.0(11)
C12–C11–C16–C1^i	175.6(7)	C3′–C4′–C4A′–C5′	−178.8(7)
C11–C16–C15–C14	.8(11)	C5′–C4A′–C8A′–O1′	177.4(7)
C1^i –C16–C15–C14	−173.8(7)	C4′–C4A′–C8A′–O1′	−3.7(11)
O5–C13–C14–C15	−178.9(7)	C5′–C4A′–C8A′–C8′	−3.5(12)
C12–C13–C14–C15	1.6(12)	C4′–C4A′–C8A′–C8′	175.4(8)
C16–C15–C14–C13	−2.3(12)	C2′–O1′–C8A′–C4A′	−1.1(11)
C2–O1–C8A–C4A	−.2(11)	C2′–O1′–C8A′–C8′	179.8(7)
C2–O1–C8A–C8	177.4(7)	C7′–C8′–C8A′–C4A′	4.0(13)
O2–C2–C3–C4	−177.3(8)	C7′–C8′–C8A′–O1′	−176.8(8)

Symmetry transformations used to generate equivalent atoms: i: 𝑥−1, 𝑦, 𝑧; ii: 1−𝑥, 𝑦−1/2, 3/2−𝑧; iv: 1−𝑥, 𝑦+1/2, 3/2−𝑧; v: 𝑥+1, 𝑦, 𝑧.