Research Article
Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex
Table 2
Selected bond lengths/
and angles/° for [
Cu
2(tidf)(
μ-NO
3)
∞]ClO
4.
| | Cu1-N1 | 1.947(3) | | Cu1-N2 | 1.984(3) | | Cu1-O1 | 1.982(2) | | Cu1-O1′ | 1.975(2) | | Cu1-O3′ | 2.237(3) | | Cu2-N3 | 1.960(3) | | Cu2-N4′′′ | 1.952(3) | | Cu2-O2 | 1.975(2) | | Cu2-O2′′′ | 1.964(2) | | Cu2-O4′′ | 2.290(3) | | Cu1⋯Cu1′ | 3.113 | | O4-N5 | 1.255(4) | | O3-N5 | 1.250(4) | | O5-N5 | 1.213(5) | | Cu1-O1-Cu1 | 103.75(9) | | O1′-Cu1-N1 | 165.85(12) | | O1-Cu1-N2 | 165.56(10) | | O1′-Cu1-O1 | 76.25(9) | | N1-Cu1-N2 | 96.71(12) | | O1-Cu1-N1 | 92.68(11) | | O1′-Cu1-N2 | 92.64(10) | | O1-Cu1-O3′ | 98.12(11) | | O1′-Cu1-O3′ | 86.37(11) | | N1-Cu1-O3′ | 104.13(14) | | N2-Cu1-O3′ | 90.22(12) | | Cu1-O11-N5 | 128.6(2) | | O3-N5-O4 | 116.7(3) | | O3-N5-O5 | 121.5(3) |
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Symmetry code: (′): , , ; (′′): , , ; (′′′): , , .
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