Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N₄O₂-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex

Table 1

Crystal data and structure refinement for [Cu₂(tidf)(μ-NO₃)_∞]ClO₄.

Empirical formula	C24H27ClCu2N5O9
Formula weight	692.04
Temperature	296(2) K
Wavelength	0.71073 Å
Crystal system	Triclinic
Space group	(−1)
Unit cell dimensions	= 8.9071(3) Å, α = 93.936(2)°.
	= 11.9325(5) Å, β = 107.870(2)°.
	= 13.6743(5) Å, γ = 105.530(2)°.
Volume	1314.59(9) Å^3
	2
Density (calculated)	1.748 Mg/m^3
Absorption coefficient	1.783 mm^−1
(000)	706
Crystal size	0.93 × 0.27 × 0.19 mm^3
Theta range for data collection	1.59 to 28.34°.
Index ranges	, ,
Reflections collected	43374
Independent reflections	6536 [(int) = 0.0207]
Completeness to theta = 28.34°	99.7%
Max. and min. transmission	0.7281 and 0.2878
Refinement method	Full-matrix least-squares on
Data/restraints/parameters	6536/0/362
Goodness-of-fit on	1.048
Final indices []	1 = 0.0482, = 0.1431
indices (all data)	= 0.0538, = 0.1494
Extinction coefficient	0.0000(6)
Largest diff. peak and hole	1.849 and −1.000 e·Å^−3