Research Article
New Copper and Oxomolybdate Robson-Type Polynuclear Macrocyclic Complexes: Structure, Spectroscopy, and Electrochemical Properties
Table 1
Selected bond lengths/
and angles/° for complexes
1 and
2.
| | Complex 1 | Complex 2 |
| | Mo1- | 2.204(9) | Cu1-N1 | 1.953(5) | | Mo1- | 1.711(12) | Cu1- | 1.969(4) | | Mo1- | 1.883(10) | Cu1- | 2.316(4) | | Mo1- | 2.142(10) | Cu2- | 2.435(5) | | Mo1-N1 | 2.230(10) | Mo2- | 1.712(4) | | Mo1-Mo2 | 3.1466(17) | Mo2- | 1.781(4) | | Mo2-Mo3 | 3.1099(15) | Mo2- | 1.790(4) | | Mo2- | 1.988(11) | Mo1- | 1.709(4) | | Mo2- | 2.000(9) | N1-Cu1-N2 | 97.5(2) | | Mo2- | 1.710(9) | -Cu1- | 77.49(17) | | Mo1-Mo2-Mo3 | 84.90(4) | -Cu2- | 83.69(17) | | Mo1-O5-Mo2 | 108.7(5) | -Cu-N1 | 92.1(2) | | Mo1-O6-Mo2 | 98.8(4) | -Cu2-N3 | 98.5(2) | | Mo1-O6-Mo3 | 162.9(5) | -Cu1-N1 | 96.5(2) | | -Mo1- | 86.6(5) | Cu1--Mo1 | 140.9(2) | | -Mo1- | 101.8(6) | O3-Mo1-O4 | 101.8(2) | | -Mo1- | 103.9(5) | O3-Mo1-O5 | 104.6(2) | | -Mo1- | 166.7(5) |
O3-Mo1-O6 | 87.53(18) |
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