Rapid Screening of 352 Pesticide Residues in Chrysanthemum Flower by Gas Chromatography Coupled to Quadrupole-Orbitrap Mass Spectrometry with Sin-QuEChERS Nanocolumn Extraction

Table 1

Information of the 352 pesticides detected in chrysanthemum flower samples by GC-Orbitrap-MS screening.

Pesticides	CAS	Molecular formula	Retention time (min)	Quantitative ion (m/z)	Qualitative ion (m/z)
					1	2
Clopyralid	1702-17-6	C6H3Cl2NO2	6.38	146.96	76.02	111.99
Dichlorvos	62-73-7	C4H7O4PCl2	7.99	184.98	186.97	144.98
Methamidophos	10265-92-6	C2H8NO2PS	8.02	141.00	112.01585	125.98
Thiofanox	39196-18-4	C9H18N2O2S	8.20	115.10	161.09	83.07
Allidochlor	93-71-0	C8H12NOCl	8.27	138.09	132.02	96.08
Dichlobenil	1194-65-6	C7H3Cl2N	8.68	170.96	100.02	172.96
EPTC	759-94-4	C9H19NOS	8.71	128.11	132.08	160.08
Dichlormid	37764-25-3	C8H11Cl2NO	8.72	172.05	108.08	165.98
2,4,6-Trichlorophenol	88-06-2	C6H3OCl3	8.73	195.92	199.92	197.92
3,5-Dichloroaniline	626-43-7	C6H5Cl2N	9.05	160.98	162.98	126.01
O-phthalimide	85-41-6	C8H5NO2	9.15	147.03	103.04	104.03
Mevinphos	7786-34-7	C7H13O6P	9.18	192.02	164.02	127.01
Acephate	30560-19-1	C4H10NO3PS	9.25	136.02	112.02	94.00
Vernolate	1929-77-7	C10H21NOS	9.30	86.06	161.09	146.10
Propham	122-42-9	C10H13NO2	9.37	137.05	179.09	120.08
Etridiazole	2593-15-9	C5H5N2OSCl3	9.40	210.95	212.95	182.92
Pebulate	1114-71-2	C10H21NOS	9.40	128.11	72.04	161.09
cis-1,2,3,6-Tetrahydrophthalimide	1469-48-3	C8H9NO2	9.57	151.06	123.07	122.06
Chloroneb	2675-77-6	C8H8O2Cl2	9.77	190.97	192.96	205.99
Tebuthiuron	34014-18-1	C9H16N4OS	9.86	156.06	89.02	171.08
Fenobucarb	3766-81-2	C12H17NO2	9.93	121.06	91.05	93.07
Pentachlorobenzene	608-93-5	C6HCl5	9.95	247.85	251.85	249.85
Isoprocarb	2631-40-5	C11H15NO2	9.98	121.06	136.09	103.05
Molinate	2212-67-1	C9H17NOS	10.01	126.09	187.10	98.10
Heptenophos	23560-59-0	C9H12CLO4P	10.30	124.00	215.05	200.02
Chlorfenprop-methyl	14437-17-3	C10H10O2Cl2	10.43	165.01	196.03	167.00
Omethoate	1113-02-6	C5H12NO4PS	10.47	156.00	110.01	140.98
Propoxur	114-26-1	C11H15NO3	10.57	110.04	82.04	152.08
Tecnazene	117-18-0	C6HNO2CL4	10.59	200.88	177.91	260.87
Propachlor	1918-16-7	C11H14NOCl	10.61	120.08	176.11	169.03
Diphenylamine	122-39-4	C12H11N	10.70	169.09	167.07	168.08
Ethoprophos	13194-48-4	C8H19O2PS2	10.77	157.96	199.00	200.01
Tributyl phosphate	126-73-8	C12H27O4P	10.78	98.98	155.05	124.10
Cycloate	1134-23-2	C11H21NOS	10.79	154.12	155.13	72.04
2,3,5,6-Tetrachloroaniline	3481-20-7	C6H3Cl4N	10.80	230.90	232.90	157.96
Atrazine-desethyl	6190-65-4	C6H10N5Cl	11.00	172.04	145.01	187.06
Dicrotophos	141-66-2	C8H16NO5P	11.07	127.02	193.03	111.07
Methabenzthiazuron	18691-97-9	C10H11N3OS	11.07	136.02	164.04	135.01
Trifluralin	1582-09-8	C13H16N3O4F3	11.08	264.02	306.07	248.03
Bendiocarb	22781-23-3	C11H13NO4	11.09	151.04	126.03	223.08
Benfluralin	1861-40-1	C13H16F3N3O4	11.12	292.05	276.06	318.11
Sulfotep	3689-24-5	C8H20O5P2S2	11.20	322.02	209.90	173.96
Cadusafos	95465-99-9	C10H23O2PS2	11.25	158.97	130.94	213.02
Tebutam	35256-85-0	C15H23NO	11.27	91.05	190.12	233.18
Promecarb	2631-37-0	C12H17NO2	11.27	135.08	107.09	150.10
Phorate	298-02-2	C7H17O2PS3	11.34	75.03	230.97	260.01
α-Hexachlorocyclohexane	319-84-6	C6H6Cl6	11.95	180.94	145.97	218.91
Atratone	1610-17-9	C9H17N5O	11.61	169.10	154.07	211.14
3,4,5-Trimethacarb	2686-99-9	C11H15NO2	11.69	121.06	91.05	136.09
Dicloran	99-30-9	C6H4Cl2N2O2	11.70	175.97	159.97	207.96
Pentachloroanisole	1825-21-4	C7H3Cl5O	11.72	264.84	238.84	279.86
Ethoxyquin	91-53-2	C14H19NO	11.72	202.12	174.09	203.13
Prometon	1610-18-0	C10H19N5O	11.73	168.09	210.13	225.16
Atrazine	1912-24-9	C8H14ClN5	11.84	200.07	202.07	173.05
Monolinuron	1746-81-2	C9H11ClN2O2	11.89	126.01	152.10	214.05
Propazine	139-40-2	C9H16N5Cl	11.92	214.08	187.06	229.11
Clomazone	81777-89-1	C12H14ClNO2	11.94	204.10	89.04	125.02
Terbumeton	33693-04-8	C10H19N5O	11.95	210.13	169.10	225.16
β-Hexachlorocyclohexane	319-85-7	C6H6Cl6	11.99	180.94	145.97	218.91
Aminocarb	2032-59-9	C11H16N2O2	12.04	151.10	136.08	150.09
Isocarbamid	30979-48-7	C8H15N3O2	12.05	142.06	130.06	113.03
Cyromazine	66215-27-8	C6H10N6	12.06	151.07	165.09	166.10
γ-Hexachlorocyclohexane	58-89-9	C6H6Cl6	12.12	180.94	145.97	218.91
Propetamphos	31218-83-4	C10H20NO4PS	12.12	138.01	193.98	222.03
Cycluron	2163-69-1	C11H22N2O	12.13	198.17	127.09	169.13
Terbuthylazine	5915-41-3	C9H16N5Cl	12.14	186.05	188.05	201.08
Terbufos	13071-79-9	C9H21O2PS3	12.16	230.97	174.91	202.94
Cyanophos	2636-26-2	C9H10NO3PS	12.17	243.01	124.98	109.00
Trietazine	1912-26-1	C9H16N5Cl	12.17	200.07	214.09	229.11
Quintozene	82-68-8	C6NO2Cl5	12.23	213.87	248.84	294.83
Fonofos	944-22-9	C10H15OPS2	12.27	246.03	137.02	108.99
Pyroquilon	57369-32-1	C11H11NO	12.28	173.08	144.08	172.08
Dinoterb	1420-07-1	C10H12N2O5	12.35	225.05	177.04	161.05
Pyrimethanil	53112-28-0	C12H13N3	12.35	198.10	199.11	183.08
Diazinon	333-41-5	C12H21N2O3PS	12.36	179.12	199.06	304.10
Flufenoxuron	101463-69-8	C21H11CLF6N2O3	12.46	331.00	268.04	296.03
Disulfoton	298-04-4	C8H19O2PS3	12.51	88.03	153.01	141.97
Paraoxon-methyl	950-35-6	C8H10NO6P	12.52	230.02	247.02	200.02
Secbumeton	26259-45-0	C10H19N5O	12.52	196.12	169.10	210.13
Aziprotryne	4658-28-0	C7H11N7S	12.53	182.05	139.01	225.08
Dinitramine	29091-05-2	C11H13F3N4O4	12.53	305.09	244.06	261.06
Fenfuram	24691-80-3	C12H11NO2	12.57	201.08	184.05	109.03
δ-Hexachlorocyclohexane	319-86-8	C6H6Cl6	12.61	180.94	145.97	218.91
Mexacarbate	315-18-4	C12H18N2O2	12.63	165.11	164.11	222.14
Isazofos	42509-80-8	C7H13N3O3PSCl	12.66	162.04	161.03	177.01
Chlorothalonil	1897-45-6	C8Cl4N2	12.71	263.88	193.94	228.91
Triallate	2303-17-5	C10H16CL3NOS	12.71	268.03	270.03	142.92
Tebupirimfos	96182-53-5	C13H23N2O3PS	12.82	234.02	261.05	276.07
Musk ambrette	83-66-9	C12H16N2O5	12.83	253.08	251.10	268.10
Oxabetrinil	74782-23-3	C12H12N2O3	12.85	73.03	103.04	114.03
Iprobenfos	26087-47-8	C13H21O3PS	12.87	204.00	171.02	246.05
Fluroxypyr	69377-81-7	C7H5N2O3FCl2	12.92	180.97	208.97	195.96
Pirimicarb	23103-98-2	C11H18N4O2	12.95	238.14	166.10	137.07
Monalide	7287-36-7	C13H18NOCl	12.95	197.06	127.01	239.11
Furmecyclox	60568-05-0	C14H21NO3	12.98	123.04	251.15	124.05
Benoxacor	98730-04-2	C11H11NO2Cl2	12.99	120.04	259.02	261.01
Pentachloroaniline	527-20-8	C6H2Cl5N	13.14	262.86	191.92	229.89
Benfuresate	68505-69-1	C12H16O4S	13.17	163.08	121.06	256.08
Dioxacarb	6988-21-2	C11H13NO4	13.17	121.03	165.05	166.06
Cyprazine	22936-86-3	C9H14N5Cl	13.24	212.07	170.02	226.08
Phosphamidon	13171-21-6	C10H19NO5PCl	13.25	138.09	193.02	264.10
Dichlorprop	120-36-5	C9H8O3Cl2	13.26	161.96	132.96	188.99
Dichlofenthion	97-17-6	C10H13CL2O3PS	13.26	222.94	250.97	279.00
Fenthion	55-38-9	C10H15O3PS2	13.26	222.94	250.97	279.00
Propanil	709-98-8	C9H9NOCl2	13.26	160.98	162.98	219.00
2,4-DB	94-82-6	C10H10O3Cl2	13.26	161.96	125.99	97.99
Chlorthiamid	1918-13-4	C7H5Cl2NS	13.29	169.98	171.98	204.95
Dimethachlor	50563-36-5	C13H18NO2Cl	13.29	197.06	148.08	134.10
Metribuzin	21087-64-9	C8H14N4OS	13.31	198.07	144.05	182.04
Dimethenamid	87674-68-8	C12H18NO2SCl	13.32	154.07	230.04	232.04
Bromobutide	74712-19-9	C15H22NOBr	13.35	119.09	120.08	232.17
Terbucarb	1918-11-2	C17H27NO2	13.44	205.16	177.13	220.18
Malaoxon	1634-78-2	C10H19O7PS	13.46	268.02	194.99	238.98
Vinclozolin	50471-44-8	C12H9Cl2NO3	13.48	178.04	212.00	285.10
Parathion-methyl	298-00-0	C8H10NO5PS	13.49	263.00	124.98	245.99
Chlorpyrifos-methyl	5598-13-0	C7H7Cl3NO3PS	13.50	285.93	287.92	289.92
Transfluthrin	118712-89-3	C15H12O2F4Cl2	13.54	163.02	127.03	335.05
Simetryn	1014-70-6	C8H15N5S	13.56	213.10	155.04	170.05
Fuberidazole	3878-19-1	C11H8N2O	13.57	184.06	156.07	183.06
Tolclofos-methyl	57018-04-9	C9H11O3PSCL2	13.61	264.98	249.96	266.98
Alachlor	15972-60-8	C14H20NO2Cl	13.67	188.11	202.12	160.11
Ametryn	834-12-8	C9H17N5S	13.67	227.12	170.05	185.07
Heptachlor	76-44-8	C10H5CL7	13.72	269.81	100.01	336.85
Prometryn	7287-19-6	C10H19N5S	13.75	241.13	184.07	199.09
Acetochlor	34256-82-1	C14H20NO2Cl	13.76	223.08	162.10	174.10
Paraoxon-ethyl	311-45-5	C10H14NO6P	13.77	275.05	247.02	139.05
Metalaxyl	57837-19-1	C15H21NO4	13.78	160.11	206.12	146.10
Tridiphane	58138-08-2	C10H7OCl5	13.84	186.97	172.96	284.92
Octachlorodipropyl ether	127-90-2	C6H6OCl8	13.89	129.91	108.96	142.92
Prosulfocarb	52888-80-9	C14H21NOS	13.89	128.11	86.06	251.13
Fenpropidin	67306-00-7	C19H31N	13.97	98.10	273.24	258.22
1-naphthylacetamide	86-86-2	C12H11NO	14.05	141.07	142.08	185.08
Dithiopyr	97886-45-8	C15H16NO2F5S2	14.05	306.05	258.05	354.06
Orbencarb	34622-58-7	C12H16NOSCl	14.08	222.09	125.02	100.08
Terbutryn	886-50-0	C10H19N5S	14.08	226.11	185.07	170.05
Spiroxamine	118134-30-8	C18H35NO2	14.11	100.11	126.13	198.15
Methiocarb	2032-65-7	C11H15NO2S	14.15	168.06	153.04	154.04
Fenitrothion	122-14-5	C9H12NO5PS	14.16	260.01	124.98	277.02
Pirimiphos-methyl	29232-93-7	C11H20N3O3PS	14.19	290.07	276.06	305.10
Methiocarb sulfone	2179-25-1	C11H15NO4S	14.22	200.05	197.03	197.03
Ethofumesate	26225-79-6	C13H18O5S	14.22	207.10	161.06	179.07
Linuron	330-55-2	C9H10N2O2Cl2	14.27	159.97	61.05	248.01
Probenazole	27605-76-1	C10H9NO3S	14.33	130.07	103.04	158.06
Noruron	18530-56-8	C13H22N2O	14.34	153.10	193.13	207.15
Quinoclamine	2797-51-5	C10H6NO2Cl	14.37	172.04	144.04	207.01
Dipropetryn	4147-51-7	C11H21N5S	14.38	255.15	222.17	184.07
Malathion	121-75-5	C10H19O6PS2	14.41	124.98	99.01	173.08
Thiobencarb	28249-77-6	C12H16ClNOS	14.44	257.06	100.08	125.02
Diethofencarb	87130-20-9	C14H21NO4	14.51	267.15	225.10	168.03
Phorate sulfoxide	2588-03-6	C7H17O3PS3	14.57	124.93	170.97	199.00
Metolachlor	51218-45-2	C15H22NO2Cl	14.61	162.13	211.08	238.10
Fenpropimorph	67564-91-4	C20H33NO	14.67	128.11	110.10	173.13
Cyanazine	21725-46-2	C9H13ClN6	14.69	225.07	212.06	240.09
Chlorpyrifos	2921-88-2	C9H11CL3NO3PS	14.71	196.92	257.90	313.96
Parathion	56-38-2	C10H14NO5PS	14.73	291.03	155.00	185.99
Flufenacet	142459-58-3	C14H13N3O2F4S	14.79	210.98	136.06	151.08
Rabenzazol	40341-04-6	C12H12N4	14.79	212.11	170.07	195.08
4,4′-Dichlorobenzophenone	90-98-2	C13H8Cl2O	14.80	138.99	110.99	249.99
Triadimefon	43121-43-3	C14H16ClN3O2	14.80	208.03	210.02	181.02
Chlorthal-dimethyl	1861-32-1	C10H6CL4O4	14.86	300.88	298.88	331.90
Dicapthon	2463-84-5	C8H9NO5PSCl	14.86	261.99	124.98	216.00
Isofenphos-oxon	31120-85-1	C15H24NO5P	14.87	200.99	229.03	272.07
Isocarbophos	24353-61-5	C11H16NO4PS	14.90	135.99	230.00	121.03
Tetraconazole	112281-77-3	C13H11Cl2F4N3O	14.92	336.05	136.01	170.98
Isobenzan	297-78-9	C9H4CL8O	15.00	407.78	274.86	310.83
Flurochloridone	61213-25-0	C12H10Cl2F3NO	15.01	174.05	311.01	313.01
Fenson	80-38-6	C12H9O3SCl	15.03	267.99	141.00	269.99
Pyracarbolid	24691-76-7	C13H15NO2	15.13	125.06	217.11	97.03
Dodemorph	1593-77-7	C18H35NO	15.13	154.12	238.22	281.27
Mgk 264	113-48-4	C17H25NO2	15.14, 15.45	164.07	209.14	210.15
Butralin	33629-47-9	C14H21N3O4	15.16	266.11	236.10	220.11
Carbaryl	63-25-2	C12H11NO2	15.16	144.06	115.05	116.06
Diphenamid	957-51-7	C16H17NO	15.21	167.09	165.07	152.06
Pirimiphos-ethyl	23505-41-1	C13H24N3O3PS	15.29	168.06	318.10	333.13
Isodrin	465-73-6	C12H8Cl6	15.36	192.94	361.88	194.93
Aldrin	309-00-2	C12H8CL6	15.36	260.86	290.93	326.91
Isopropalin	33820-53-0	C15H23N3O4	15.36	280.13	238.08	264.13
Cyprodinil	121552-61-2	C14H15N3	15.41	224.12	225.13	208.09
Isofenphos-methyl	99675-03-3	C14H22NO4PS	15.42	199.02	230.99	241.06
Octachlorostyrene	29082-74-4	C8Cl8	15.54	305.81	270.84	379.74
Metazachlor	67129-08-2	C14H16ClN3O	15.56	209.06	133.09	211.06
Dimethametryn	22936-75-0	C11H21N5S	15.58	212.10	185.07	240.13
Pendimethalin	40487-42-1	C13H19N3O4	15.60	252.10	191.07	162.08
Disulfoton-sulfone	2497-6-5	C8H19O4PS3	15.62	153.01	124.98	213.02
Phorate sulfone	2588-04-7	C7H17O4PS3	15.62	199.00	124.98	170.97
Terbufos sulfone	56070-16-7	C9H21O4PS3	15.62	153.01	199.00	263.97
Paclobutrazol	76738-62-0	C15H20ClN3O	15.64	236.06	138.02	167.03
Penconazole	66246-88-6	C13H15N3Cl2	15.64	248.09	160.97	158.98
Chlozolinate	84332-86-5	C13H11NO5Cl2	15.72	186.96	260.98	188.96
Pyrifenox	88283-41-4	C14H12N2OCl2	15.72	262.01	186.96	227.04
Tolylfluanid	731-27-1	C10H13N2O2FS2Cl2	15.75	237.97	181.08	239.96
Fosthiazate	98886-44-3	C9H18NO3PS2	15.80	195.01	166.02	226.98
Phosfolan	947-02-4	C7H14NO3PS2	15.80	139.96	167.99	266.98
Allethrin	584-79-2	C19H26O3	15.84	123.12	91.05	136.09
Isofenphos	25311-71-1	C15H24NO4PS	15.84	213.03	184.99	216.97
Captan	133-06-2	C9H8NO2SCl3	15.85	149.05	105.03	116.91
Fipronil	120068-37-3	C12H4Cl2F6N4OS	15.88	366.94	368.94	212.95
Diclocymet	139920-32-4	C15H18N2OCl2	15.90, 16.38	221.05	172.99	277.11
Quinalphos	13593-03-8	C12H15N2O3PS	15.92	146.05	157.08	173.07
Phenthoate	2597-03-7	C12H17O4PS2	15.93	273.99	121.01	245.99
Triadimenol	55219-65-3	C14H18N3O2Cl	15.94	168.11	112.05	169.12
Dinobuton	973-21-7	C14H18N2O7	16.00	211.03	163.03	205.06
Furalaxyl	57646-30-7	C17H19NO4	16.03	242.12	152.07	146.10
Crotoxyphos	7700-17-6	C14H19O6P	16.06	193.03	127.02	105.07
Procymidone	32809-16-8	C13H11NO2Cl2	16.11	283.02	96.06	255.02
Chlorbenside	103-17-3	C13H10SCl2	16.15	125.02	127.01	267.99
Chlorflurenol-methyl	2536-31-4	C15H11O3Cl	16.22	215.03	152.06	274.04
Chlordane	5103-71-9	C10H6Cl8	16.32, 16.58	372.83	376.82	374.82
Methidathion	950-37-8	C6H11N2O4PS3	16.33	145.01	85.04	147.00
Haloxyfop-methyl	69806-40-2	C16H13ClF3NO4	16.39	375.05	288.00	179.98
Bromophos-ethyl	4824-78-6	C10H12O3PSCl2Br	16.41	300.85	241.87	358.91
Procyazine	32889-48-8	C10H13N6Cl	16.43	210.05	212.05	252.09
Disulfoton-sulfoxide	2497-07-6	C8H19O3PS3	16.61	183.98	124.98	167.98
Tetrachlorvinphos	22248-79-9	C10H9O4PCl4	16.63	328.93	203.93	239.89
Endosulfan	959-98-8	C9H6O3SCl6	16.67, 18.37	236.84	169.97	159.98
Mepanipyrim	110235-47-7	C14H13N3	16.69	222.10	221.09	223.11
Butachlor	23184-66-9	C17H26NO2Cl	16.74	176.11	188.11	160.11
Ditalimfos	5131-24-8	C12H14NO4PS	16.81	242.98	208.97	271.00
TCMTB	21564-17-0	C9H6N2S3	16.87	179.99	166.99	237.97
Trans-nonachlor	39765-80-5	C10H5Cl9	16.90	408.78	404.79	271.81
Chlorfenson	80-33-1	C12H8CL2O3S	16.94	174.96	176.96	301.96
Fenamiphos	22224-92-6	C13H22NO3PS	16.95	303.11	260.05	217.01
Picoxystrobin	117428-22-5	C18H16NO4F3	16.96	303.05	173.06	335.08
Napropamide	15299-99-7	C17H21NO2	17.00	271.16	72.08	115.05
Hexaconazole	79983-71-4	C14H17Cl2N3O	17.06	213.99	231.03	174.97
Flutolanil	66332-96-5	C17H16NO2F3	17.07	173.02	281.07	323.11
Prothiophos	34643-46-4	C11H15O2PS2Cl2	17.18	308.99	238.92	266.95
Isoprothiolane	50512-35-1	C12H18O4S2	17.19	117.99	161.98	290.06
Profenofos	41198-08-7	C11H15BrClO3PS	17.26	338.96	205.91	207.91
Tricyclazole	41814-78-2	C9H7N3S	17.35	189.03	135.01	161.02
Pretilachlor	51218-49-6	C17H26NO2Cl	17.36	162.13	202.12	238.10
Dieldrin	60-57-1	C12H8CL6O	17.44	262.86	81.03	260.86
Oxadiazon	19666-30-9	C15H18N2O3Cl2	17.51	174.96	302.02	344.07
Iprovalicarb	140923-17-7	C18H28N2O3	17.52, 17.82	134.10	116.07	158.12
Carboxin	5234-68-4	C12H13NO2S	17.60	235.07	218.04	143.02
Myclobutanil	88671-89-0	C15H17ClN4	17.60	179.02	150.01	245.06
p,p'-Dichlorodiphenyldichloroethylene	72-55-9	C14H8Cl4	17.64	315.94	247.99	245.99
Buprofezin	69327-76-0	C16H23N3OS	17.68	175.09	171.10	249.11
Imazalil	35554-44-0	C14H14Cl2N2O	17.70	174.95	172.96	158.98
Flusilazole	85509-19-9	C16H15N3F2Si	17.70	233.06	206.05	314.10
Methoprotryne	841-06-5	C11H21N5OS	17.72	256.12	184.07	212.10
Azaconazole	60207-31-0	C12H11N3O2Cl2	17.75	216.98	144.96	174.95
Bupirimate	41483-43-6	C13H24N4O3S	17.79	208.14	193.14	273.10
Imazamethabenz-methyl	81405-85-8	C16H20N2O3	17.82	144.04	176.07	245.09
Kresoxim-methyl	143390-89-0	C18H19NO4	17.83	116.05	131.07	206.08
Metamitron	41394-05-2	C10H10N4O	17.85	174.09	173.08	202.08
Isoxathion	18854-01-8	C13H16NO4PS	17.97	177.02	159.01	313.05
Aramite	140-57-8	C15H23O4SCl	17.98	185.00	175.11	319.08
Nitrofen	1836-75-5	C12H7Cl2NO3	18.02	282.98	284.98	202.02
Endrin	72-20-8	C12H8CL6O	18.09	242.95	280.93	316.90
Endrin aldehyde	7421-93-4	C12H8OCl6	18.09	242.95	280.93	344.90
Ancymidol	12771-68-5	C15H16N2O2	18.12	228.90	107.02	215.08
Perthan	72-56-0	C18H20Cl2	18.15	223.15	178.08	167.09
Chlorfenapyr	122453-73-0	C15H11BRCLF3N2O	18.19	247.05	363.94	361.94
Chloropropylate	5836-10-2	C17H16O3Cl2	18.38	138.99	110.99	251.00
Chlorobenzilate	510-15-6	C16H14O3Cl2	18.38	138.99	251.00	252.99
Fenthion sulfoxide	3761-41-9	C10H15O4PS2	18.51	294.01	278.99	152.98
Diniconazole	83657-24-3	C15H17N3OCl2	18.55	268.00	234.04	165.01
Flamprop-isopropyl	52756-22-6	C19H19NO3FCl	18.63	276.06	105.03	156.00
p,p'-Dichlorodiphenyldichloroethane	72-54-8	C14H10Cl4	18.66	235.01	199.03	165.07
Aclonifen	74070-46-5	C12H9CLN2O3	18.68	264.03	182.06	212.06
o,p'-Dichlorodiphenyltrichloroethane	789-02-6	C14H9Cl5	18.76	235.00	165.07	237.00
Oxadixyl	77732-09-3	C14H18N2O4	18.78	233.09	163.10	132.08
Ethion	563-12-2	C9H22O4P2S4	18.82	230.97	202.94	153.01
Mepronil	55814-41-0	C17H19NO2	19.07	119.05	210.07	269.14
Triazophos	24017-47-8	C12H16N3O3PS	19.22	162.07	257.00	172.09
Azamethiphos	35575-96-3	C9H10ClN2O5PS	19.34	182.99	214.97	323.97
Ofurace	58810-48-3	C14H16NO3Cl	19.39	232.10	186.09	281.08
Carbophenothion	786-19-6	C11H16O2PS3Cl	19.47	341.97	170.97	199.00
Benalaxyl	71626-11-4	C20H23NO3	19.55	148.11	176.11	206.12
Tepraloxydim	149979-41-9	C17H24NO4Cl	19.55	164.07	136.04	108.04
Diofenolan	63837-33-2	C18H20O4	19.56, 19.77	186.07	131.05	225.09
Cyanofenphos	13067-93-1	C15H14NO2PS	19.60	141.01	169.04	185.02
Edifenphos	17109-49-8	C14H15O2PS2	19.60	172.98	186.05	310.02
Quinoxyfen	124495-18-7	C15H8NOFCl2	19.63	306.99	237.06	161.00
Endosulfan sulfate	1031-07-8	C9H6CL6O4S	19.69	271.81	236.84	269.81
Propiconazol	60207-90-1	C15H17Cl2N3O2	19.70, 19.91	172.95	259.03	261.03
Norflurazon	27314-13-2	C12H9N3OF3Cl	19.74	303.04	173.03	302.03
Fenhexamid	126833-17-8	C14H17Cl2NO2	19.79	176.97	178.97	301.06
p,p'-Dichlorodiphenyltrichloroethane	50-29-3	C14H9Cl5	19.84	235.00	199.03	165.07
Trifloxystrobin	141517-21-7	C20H19F3N2O4	19.92	116.05	190.05	186.05
Hexazinone	51235-04-2	C12H20N4O2	20.17	171.09	71.06	128.08
Tebuconazol	107534-96-3	C16H22ClN3O	20.26	250.07	125.02	163.03
Chloridazon	1698-60-8	C10H8ClN3O	20.26	220.03	221.04	222.02
Nuarimol	63284-71-9	C17H12N2OFCl	20.28	235.03	203.06	314.06
Diclofop-methyl	51338-27-3	C16H14Cl2O4	20.39	340.03	254.98	252.98
Triphenyl phosphate	115-86-6	C18H15O4P	20.49	325.06	169.06	233.04
Piperonyl butoxide	51-03-6	C19H30O5	20.62	176.08	161.06	177.09
Oxycarboxin	5259-88-1	C12H13NO4S	20.68	175.01	250.03	267.06
Resmethrin	10453-86-8	C22H26O3	20.70	143.09	128.06	171.08
Zoxamide	156052-68-5	C14H16NO2Cl3	20.83	186.97	258.04	242.01
Mefenpyr-diethyl	135590-91-9	C16H18Cl2N2O4	21.02	271.00	227.01	299.03
Benzoylprop-ethyl	22212-55-1	C18H17NO3Cl2	21.12	105.03	292.03	260.02
Spiromesifen	283594-90-1	C23H30O4	21.14	254.13	231.10	226.13
Endrin ketone	53494-70-5	C12H8OCl6	21.16	314.91	281.93	242.95
Fenamiphos sulfone	31972-44-8	C13H22NO5PS	21.27	292.04	320.07	214.06
Bromuconazole	116255-48-2	C13H12BrCl2N3O	21.31, 22.12	172.95	294.91	174.95
Fenpiclonil	74738-17-3	C11H6N2Cl2	21.32	235.99	201.02	237.99
Phosmet	732-11-6	C11H12NO4PS2	21.37	160.04	104.03	133.03
Bromopropylate	18181-80-1	C17H16O3Br2	21.48	184.94	182.94	338.90
Tetramethrin	7696-12-0	C19H25NO4	21.61	164.07	107.05	123.12
Picolinafen	137641-05-5	C19H12N2O2F4	21.61	238.05	145.03	376.08
Bifenthrin	82657-04-3	C23H22ClF3O2	21.64	181.10	165.07	182.10
Piperophos	24151-93-7	C14H28NO3PS2	21.68	122.10	140.11	320.14
4,4′-Methoxychlor	72-43-5	C16H15O2CL3	21.73	227.11	212.08	228.11
Bifenazate	149877-41-8	C17H20N2O3	21.73	300.15	258.10	196.08
Fenpropathrin	39515-41-8	C22H23NO3	21.83	181.06	209.08	265.07
Etoxazole	153233-91-1	C21H23F2NO2	21.91	300.12	187.11	330.13
Tebufenpyrad	119168-77-3	C18H24N3OCl	21.94	333.16	171.03	276.09
Fenamidone	161326-34-7	C17H17N3OS	21.95	268.09	206.07	238.11
Dicofol	115-32-2	C14H9CL5O	21.98	138.99	199.03	140.99
Metconazole	125116-23-6	C17H22N3OCl	21.99	125.02	145.06	250.11
Fenazaquin	120928-09-8	C20H22N2O	22.00	145.10	117.07	160.12
Tetradifon	116-29-0	C12H6O2SCl4	22.36	226.89	228.89	158.97
Furathiocarb	65907-30-4	C18H26N2O5S	22.54	163.08	194.04	325.13
Phosalone	2310-17-0	C12H15NO4PS2Cl	22.68	182.00	121.04	366.99
Pyriproxyfen	95737-68-1	C20H19NO3	22.88	136.08	226.10	137.08
Mirex	2385-85-5	C10Cl12	22.96	271.81	269.81	331.81
Mefenacet	73250-68-7	C16H14N2O2S	23.04	192.01	136.02	120.08
Cyhalothrin	68085-85-8	C23H19ClF3NO3	23.13, 23.49	141.05	197.03	161.06
Tralkoxydim	87820-88-0	C20H27NO3	23.17	137.04	227.13	283.16
Fenarimol	60168-88-9	C17H12N2OCl2	23.58	251.00	219.03	252.99
Trifenmorph	1420-06-0	C23H23NO	23.65	243.12	228.09	239.09
Azinphos-ethyl	2642-71-9	C12H16N3O3PS2	23.85	132.04	104.05	160.05
Pyrazophos	13457-18-6	C14H20N3O5PS	23.88	221.08	265.09	193.05
Acrinathrin	101007-06-1	C26H21F6NO5	23.90	181.06	208.08	289.07
Fluoroglycofen-ethyl	77501-90-7	C18H13NO7F3Cl	23.96	343.99	223.04	447.03
Fenoxaprop-ethyl	66441-23-4	C18H16NO5Cl	24.25	288.04	182.06	361.07
Bitertanol	55179-31-2	C20H23N3O2	24.59	170.07	168.11	171.08
Spirodiclofen	148477-71-8	C21H24Cl2O4	24.74	259.05	312.03	156.96
Permethrin	61949-76-6	C21H20CL2O3	24.78, 25.03	183.08	163.01	127.03
Pyridaben	96489-71-3	C19H25ClN2OS	24.96	147.12	117.07	309.08
Fluquinconazole	136426-54-5	C16H8N5OFCl2	25.13	340.04	298.02	286.02
Coumaphos	56-72-4	C14H16CLO5PS	25.16	362.01	210.01	225.98
Prochloraz	67747-09-5	C15H16N3O2Cl3	25.28	180.11	265.95	308.00
Butafenacil	134605-64-4	C20H18N2O6F3Cl	25.63	331.01	123.99	179.98
Prallethrin	23031-36-9	C19H24O3	25.83	123.12	81.07	105.07
Cyfluthrin	68359-37-5	C22H18NO3FCl2	25.94, 26.13, 26.26, 26.35	206.06	199.06	163.01
Cypermethrin	52315-07-8	C22H19Cl2NO3	26.51, 26.71, 26.83, 26.93	181.06	163.01	127.03
Boscalid	188425-85-6	C18H12Cl2N2O	26.53	342.03	111.99	139.99
Quizalofop-ethyl	76578-14-8	C19H17CLN2O4	26.75	372.09	243.03	163.01
Flucythrinate	70124-77-5	C26H23F2NO4	26.93, 27.30	157.05	199.09	225.08
Etofenprox	80844-07-1	C25H28O3	27.03	163.11	135.08	164.12
Pyridalyl	179101-81-6	C18H14NO3F3Cl4	27.18	204.06	148.04	176.03
Fenvalerate	51630-58-1	C25H22NO3Cl	28.21, 28.61	419.13	125.02	167.06
Flumioxazin	103361-09-7	C19H15FN2O4	28.25	354.10	259.05	326.11
Pyraclostrobin	175013-18-0	C19H18N3O4Cl	28.34	132.04	104.05	164.07
Tau-fluvalinate	102851-06-9	C26H22ClF3N2O3	28.62, 28.75	250.06	252.06	205.99
Difenoconazole	119446-68-3	C19H17N3O3Cl2	28.95, 29.07	323.02	266.98	264.98
Deltamethrin	52918-63-5	C22H19Br2NO3	29.21, 29.56	171.99	173.99	252.90
Azoxystrobin	131860-33-8	C22H17N3O5	30.02	344.10	372.10	388.09
Dimethomorph	110488-70-5	C21H22ClNO4	30.06	301.06	303.06	387.12