Quality Evaluation of Traditional Chinese Medicine Prescription in Naolingsu Capsule Based on Combinative Method of Fingerprint, Quantitative Determination, and Chemometrics

Table 1

MS parameters of the fourteen components.

Analytes	tR (min)	m/z quantification analyses	m/z identification analyses	Dp (V)	Ce (eV)
DA	11.32	482.4	437.6/421.0^q	−235	−54/−54
PAC	11.73	481.4	437.5/419.3^q	−265	−48/−48
ATA	12.60	527.4	465.2/405.4^q	−300	−54/−54
XS	4.30	400.2	238.2/161.2^q	−40	−19/−18
XZ	5.04	237.9	208.0/196.0^q	−40	−22/−21
JA	8.16	1205.7	1072.9/749.8^q	−220	−60/−75
JB	8.96	1042.7	911.7/749.7^q	−220	−50/−60
MPA	10.49	341.1	206.0/178.1^q	−110	−35/−40
RD	2.45	685.3	262.1/178.9^q	−110	−28/−33
GRF	8.14	799.6	637.7/475.4^q	−220	−37/−50
GRG	6.69	799.6	637.7/475.4^q	−220	−37/−50
GRR	6.69	945.6	799.7/637.6^q	−220	−44/−53
GRB	8.96	1107.7	945.6/782.5^q	−220	−60/−65
PX	5.04	567.2	417.2/297.1^q	−100	−41/−35
Ion source (GS1)			50
Ion source (GS2)			50
Curtain gas (CUR)			30
Collision gas (CAD)			8
EP			−14
CXP			−22

^qProduct ion used for quantification.