FTIR transmission spectra of a-:H(i) films with different process temperatures. O in the film tends to be bonded in higher order configuration with increasing temperature. The diminishing peak at 640 cm−1 and 2000 cm−1 indicates the effusion of H atoms. The disappearance of doublet at 845 cm−1 and 890 cm−1 indicates the optimised temperature. The lines are guide to the eye.