Synthesis, Characterisation, Crystal Structure, and Antimicrobial and Larvicidal Studies of [Cu(2,2′-bipy)₂SO₄]·3CH₄N₂O·2H₂O

Table 1

Crystal data and structure refinement for the complex Cu(2,2′-bipySO₄]·3CH₄N₂O·2H₂O.

Empirical formula	C23H32CuN10O9S
Formula weight	688.19
Temperature/K	293(2)
Crystal system	Monoclinic
Space group	C2/c
/Å	20.155(4)
/Å	20.858(4)
/Å	14.425(3)
/°	90.00
/°	96.51(3)
/°	90.00
Volume/Å^3	6025(2)
	8
mg/mm^3	1.517
/mm^−1	0.861
(000)	2856.0
Crystal size/mm^3	0.23 0.19 0.15
2Θ range for data collection	3.84 to 56.62°
Index ranges	−25 ≤ ≤ 19, −27 ≤ ≤ 27, and −19 ≤ ≤ 12
Reflections collected	21903
Independent reflections	6624 [(int) = 0.0310]
Data/restraints/parameters	6624/0/461
Goodness of fit on	1.031
Final indexes [ > 2()]	= 0.0360, = 0.0878
Final indexes [all data]	= 0.0642, = 0.0990
Largest diff. peak/hole/e Å^−3	0.32/−0.34