Research Article
Nickel (II) and Iron (II) Complexes with Azole Derivatives: Synthesis, Crystal Structures and Antifungal Activities
Table 1
Crystal data and structure refinement for compounds 1 and 2.
| | Compound | ( ) | (2) |
| | Empirical formula | C20H10ClNNiO | C30H22FeN2S2 | | FW | 374.14 | 529.97 | | (K) | 293(2) | 293(2) | | Space group | P21/n | | | Wavelength (Å) | 0.71073 | 0.71073 | | Crystal system | Monoclinic | Monoclinic | | Unit cell dimensions | | | | (Å) | 9.937(2) | 16.839(3) | | (Å) | 14.363(3) | 9.671(19) | | (Å) | 10.9218(3) | 18.496(6) | | (Å3) | 1532.35(8) | 2853.78(18) | | 4 | 4 | | (g/cm−3) | 1.624 | 1.361 | | μ (mm−1) | 0.092 | 0.091 | | (000) | 532 | 528 | | Crystal size (mm3) | 0.20 × 0.25 × 0.13 | 0.20 × 0.20 × 0.25 | | range (deg) | 1.77–27.48 | 1.60–27.48 | | Index range (, , ) | −10/10, 13/12, −28/28 | −8/8, −8/8, −25/29 | | Reflection collected | 4896 | 4791 | Independent reflections
() | 2095
0.1111 | 2144
0.0187 | | Data/restraints/parameter | 3501/1/224 | 2501/0/187 | | Goodness-of-fit on | 0.918 | 1.034 | | Final indices [ > 2> ()] | = 0.1435, | = 0.0536, | | = 0.4235 | = 0.1231 | | indices (all data) | = 0.1604, | = 0.0865, | | = 0.4365 | = 0.1335 | | Largest diff. peak and hole (e Å−3) | 0.243 and −0.275 | 0.663 and −0.557 |
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