Research Article

Biodegradation Kinetics of Benzene and Naphthalene in the Vadose and Saturated Zones of a (Semi)-arid Saline Coastal Soil Environment

Table 3

Mass balance between oxygen and nitrate consumption and petroleum hydrocarbon degradation.

CompoundSoil and environmental conditionElectron acceptorObserved lowest concentration of an electron acceptor in biotic samples (mmol L-1)Observed maximum consumption of an electron acceptor (mmol L-1)Maximum concentration of PHCs biodegraded based on maximum electron acceptor consumed# (mmol L-1)Observed actual maximum concentration of PHCs biodegraded in the experiment including an assumed contribution of SRB (mmol L-1)

BenzeneA1 (low salinity)O20.0050.0530.0070.051
NO3-00.0830.006
A2 (low salinity)O20.0090.0490.0070.062
NO3-000
A3 (low salinity)O20.0200.0380.0050.050
NO3-00.0680.005
A3 (high salinity)O20.0110.0480.0060.046
NO3-No dataNo dataNo data

NaphthaleneA1 (low salinity)O200.0580.0050.009
NO3-00.0680.003
A2 (low salinity)O20.0370.0220.0020.025
NO3-00.0370.002
A3 (low salinity)O20.0040.0540.0050.019
NO3-00.0730.003
A3 (high salinity)O20.0250.0330.0030.012
NO3-No dataNo dataNo data

The evaluation was performed with the mean concentrations of triplicate biotic samples and duplicate controls. The consumption or losses of O2 and NO3- are reductions from the initial concentration of O2 and concentrations of NO3- in controls, respectively. #The calculations were based on the stoichiometry ratios in Equations (1) and (2) and (5) and (6).