Research Article

Stability Constants of Mixed Ligand Complexes of Nickel(II) with Adenine and Some Amino Acids

Table 1

The protonation constants of the ligands at 25.0 ± 0.1°C, = 0.1 mol·L−1 KNO3.


Ade(A)9.60 ± 0.064.18 ± 0.07
9.60 [24]3.90 [24]
9.62 [25]4.20 [25]
9.92 [26]4.19 [26]

L-Asp(B)9.61 ± 0.033.74 ± 0.032.00 ± 0.03
9.64 [25]3.70 [25]1.98 [25]
9.82 [27]3.86 [27]2.10 [27]
9.48 [28]3.87 [28]2.48 [28]

L-Glu(B)9.57 ± 0.054.16 ± 0.052.19 ± 0.05
9.58 [25]4.14 [25]2.16 [25]
9.41 [27]4.15 [27]2.65 [27]
9.98 [29]4.37 [29]2.05 [29]

L-Asn(B)8.78 ± 0.022.17 ± 0.02
8.73 [25]2.16 [25]
8.45 [24]1.70 [24]

L-Leu(B)9.52 ± 0.052.31 ± 0.05
9.56 [25]2.34 [25]
9.58 [30]2.32 [30]

L-Phe(B)9.14 ± 0.072.19 ± 0.07
9.10 [25]2.18 [25]
9.75 [31]2.14 [31]

L-Trp(B)9.38 ± 0.032.31 ± 0.03
9.33 [25]2.28 [25]
9.14 [32]2.22 [32]

Uncertainties are expressed as ± one standard deviation.