Research Article
Stability Constants of Mixed Ligand Complexes of Nickel(II) with Adenine and Some Amino Acids
Table 1
The protonation constants of the ligands at 25.0 ± 0.1°C,
= 0.1 mol·L
−1 KNO
3.
| | | | |
| Ade(A) | 9.60 ± 0.06 | 4.18 ± 0.07 | | 9.60 [24] | 3.90 [24] | | 9.62 [25] | 4.20 [25] | | 9.92 [26] | 4.19 [26] | |
| L-Asp(B) | 9.61 ± 0.03 | 3.74 ± 0.03 | 2.00 ± 0.03 | 9.64 [25] | 3.70 [25] | 1.98 [25] | 9.82 [27] | 3.86 [27] | 2.10 [27] | 9.48 [28] | 3.87 [28] | 2.48 [28] |
| L-Glu(B) | 9.57 ± 0.05 | 4.16 ± 0.05 | 2.19 ± 0.05 | 9.58 [25] | 4.14 [25] | 2.16 [25] | 9.41 [27] | 4.15 [27] | 2.65 [27] | 9.98 [29] | 4.37 [29] | 2.05 [29] |
| L-Asn(B) | 8.78 ± 0.02 | 2.17 ± 0.02 | | 8.73 [25] | 2.16 [25] | | 8.45 [24] | 1.70 [24] | |
| L-Leu(B) | 9.52 ± 0.05 | 2.31 ± 0.05 | | 9.56 [25] | 2.34 [25] | | 9.58 [30] | 2.32 [30] | |
| L-Phe(B) | 9.14 ± 0.07 | 2.19 ± 0.07 | | 9.10 [25] | 2.18 [25] | | 9.75 [31] | 2.14 [31] | |
| L-Trp(B) | 9.38 ± 0.03 | 2.31 ± 0.03 | | 9.33 [25] | 2.28 [25] | | 9.14 [32] | 2.22 [32] | |
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Uncertainties are expressed as ± one standard deviation.
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