Research Article
Axially Ligated Zirconium(IV) Tetraphenylporphyrin: Synthesis, Characterization, and Biological Activity
Table 2
Optical absorption data of Zr(TPP)(Y)(X) in different solvents.
| Compounds | Solvent | (nm), (M−1 cm−1) | (cm−1) |
| | | | | | |
| Zr(TPP)(acac)(phO) | Acetone | 413.1 | 500.5 | 535.7 | 579.9 | 1309.3 | 1067.2 | 0.235887 | 5.074 | 4.183 | 4.796 | 5.009 | | | | CH2Cl2 | 409.4 | 496.3 | 532.2 | 575.8 | 1241.6 | 1020.7 | 0.197404 | 5.030 | 4.126 | 4.721 | 4.951 | | | | CHCl3 | 411.3 | 498.5 | 533.4 | 577.5 | 1278.1 | 1041.1 | 0.207468 | 5.042 | 4.139 | 4.735 | 4.964 | | | |
| Zr(TPP)(acac)(p-OCH3phO) | Acetone |
414.2 | 501.5 | 536.8 | 580.9 | 1340.2 | 1085.9 | 0.252492 | 5.101 | 4.197 | 4.812 | 5.031 | | | | CH2Cl2 | 409.8 | 496.4 | 530.6 | 574.9 | 1279.9 | 1039.3 | 0.207586 | 5.057 | 4.172 | 4.749 | 4.965 | | | | CHCl3 | 411.9 | 498.3 | 534.2 | 578.5 | 1312.6 | 1062.4 | 0.213671 | 5.063 | 4.178 | 4.765 | 4.968 | | | |
| Zr(TPP)(acac)(p-CH3phO) | Acetone | 412.9 | 501.4 | 535.1 | 580.8 | 1270.3 | 1035.2 | 0.219019 | 5.056 | 4.168 | 4.788 | 4.990 | | | | CH2Cl2 | 409.7 | 496.3 | 532.3 | 576.4 | 1218.3 | 992.6 | 0.183752 | 5.002 | 4.131 | 4.718 | 4.932 | | | | CHCl3 | 411.2 | 499.1 | 533.8 | 577.9 | 1236.8 | 1007.9 | 0.194033 | 5.012 | 4.147 | 4.729 | 4.949 | | | |
| Zr(TPP)(acac)(p-NO2phO) | Acetone | 410.9 | 500.2 | 536.1 | 582.5 | 1271.2 | 1033.2 | 0.256245 | 5.050 | 4.156 | 4.728 | 4.901 | | | | CH2Cl2 | 408.6 | 495.2 | 531.5 | 576.3 | 1218.1 | 991.3 | 0.191456 | 5.010 | 4.111 | 4.513 | 4.899 | | | | CHCl3 | 410.1 | 498.9 | 537.6 | 577.7 | 1235.9 | 1006.7 | 0.198565 | 5.006 | 4.124 | 4.279 | 4.999 | | | |
| Zr(TPP)(acac)(-naphtholate) | Acetone | 413.5 | 500.4 | 535.2 | 581.9 | 1272.3 | 1034.2 | 0.232365 | 5.045 | 4.116 | 4.718 | 4.912 | | | | CH2Cl2 | 411.5 | 497.8 | 535.6 | 577.6 | 1217.3 | 9956 | 0.182536 | 5.013 | 4.113 | 4.518 | 4.922 | | | | CHCl3 | 413.5 | 498.3 | 535.8 | 578.9 | 1235.8 | 1005.3 | 0.195632 | 5.102 | 4.127 | 4.739 | 4.948 | | | |
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