Transient Exciplex Formation Electron Transfer Mechanism
Figure 12
Dependences of (top) and log () (bottom) on for quenching of excited singlet states of cyanoaromatic compounds by methoxybenzenes and methylnaphthalenes in MeCN (according to the experimental data [15]). Best plots are shown for simulation of the experimental dependence by (3) ( eV) (dash line) and by concatenated mechanism (16) (solid line). Dotted line shows thermodynamic limit for ET.