Potential Energy Surfaces Using Algebraic Methods Based on Unitary Groups

Table 8

Observed and calculated relative intensities of the stretching vibrational bands in arsine from [65].

Local state	𝜈calc/cm^−1	𝐼obs	𝐼calc	Halonen et al. [124]	Pluchart et al. [47]
		Symmetry 𝐴1
(100)	2115.13	1.0^a	1.0	1	1.0
(200)	4165.79	0.021	0.068	0.022	0.0209
(110)	4238.94	—	1.14×10^−3	0.13×10^−3	—
(300)	6136.07	0.32×10^−3	1.32×10^−3	0.49×10^−3	0.47×10^−3
(210)	6277.63	0.28×10^−4	0.07×10^−4	0.0055×10^−4	—
(400)	8027.32	0.15 ×10^−4	0.129×10^−4	0.071×10^−4	0.12×10^−4
		Symmetry 𝐸
(100)	2126.81	1.0^a	1.0	1.0	1.0
(200)	4168.75	0.021	0.069	0.022	0.0209
(011)	4248.66	—	2.64×10^−4	0.58×10^−4	—
(300)	6136.36	0.32 ×10^−3	1.32×10^−3	0.49×10^−3	0.47×10^−3
(012)	6283.43	—	1.51×10^−6	0.51×0^−6	—
(120)	6295.01	0.14×10^−4	0.015×10^−4	0.0032×10^−4	—
(400)	8027.35	0.15×10^−4	0.128×10^−4	0.071×10^−4	0.12×10^−4

^aScaled value.