Contact and Distant Luminescence Quenching in Solutions

Figure 30

Fitting the theoretical efficiencies (solid lines) to the real experimental data for total (▴) and triplet (■) recombination efficiencies, using the exponential models for both the ionization and recombination rates. Parameters obtained from the best fit are the following: 𝑊_𝑖=29.12ns⁻¹, 𝑊_𝑠=77ns⁻¹=1.2⋅𝑊_𝑡, 𝑙_𝐼=0.81Å, 𝑙_𝑅=1.24Å, 𝑘_𝑠=0.75ns⁻¹, 𝜎=7.5Å. Reproduced from Figure 3.75 of the recent review [16].