Contact and Distant Luminescence Quenching in Solutions
Figure 20
The dependence
on diffusion of the effective electron transfer radius, .
(a) The experimental data, indicated by circles, is approximated by a thin line
representing the contact Smoluchowski-Collins-Kimball approach and by thick
line depicting the same dependence, but for the exponential transfer rate from
(119) with and .
(b) The same but in a wider diffusion diapason. The dashed-dotted line at the
bottom represents the high viscosity asymptote of the same dependence but for
the Marcus transfer rate. (From [79]).